22/10/2025
INTRINSIC AND EXTRINSIC SEMICONDUCTORS
Intrinsic and extrinsic semiconductors differ in their purity: an intrinsic semiconductor is pure, with an equal number of electrons and holes, while an extrinsic semiconductor is a pure material with impurities added through doping to control its electrical conductivity. Doping creates more charge carriers, leading to higher, more controllable conductivity than intrinsic semiconductors, which have very low conductivity at room temperature.
INTRINSIC SEMICONDUCTORS
➡️Purity:
Pure, undoped semiconductors, meaning they have no impurities added.
➡️ Charge carriers:
Have an equal number of free electrons and holes, as both are generated by thermal energy.
➡️ Conductivity:
Low electrical conductivity because the number of charge carriers is low.
➡️ Examples:
High-purity silicon and germanium. Behavior: Acts like an insulator at (0K) (absolute zero).
EXTRINSIC SEMICONDUCTORS
• Purity:
Impure, created by doping an intrinsic semiconductor with a small amount of impurities.
• Charge carriers:
Have a majority of one type of charge carrier (either electrons or holes), which is controlled by the type of dopant added.
• Conductivity:
High electrical conductivity and controlled electrical properties.
TYPES OF EXTRINSIC SEMICONDUCTORS:
1. N-type:
Doped with impurities that have more valence electrons than the semiconductor (e.g., adding phosphorus to silicon), creating an excess of free electrons.
2. P-type:
Doped with impurities that have fewer valence electrons (e.g., adding boron to silicon), creating an excess of "holes".
Applications:
The basis for most electronic devices like diodes, transistors, and integrated circuits.