15/09/2025
Q: What kind of additives are antioxidants used in blown film? What role do antioxidants play? How do you choose the right antioxidant?
A: Antioxidants are a very useful additive used in blown film production. Those of us working in blown film have all encountered the problem of blown film aging and yellowing, or even yellowing and aging after a period of storage. How can this problem be solved? This is where antioxidants come in. These additives are commonly used in high-end film products. Properly used, they can effectively improve the physical properties of blown film.
1. First, what are antioxidants? While this article focuses primarily on blown film, antioxidants are actually widely used in plastic products.
2. Simply put, antioxidants are a class of chemical substances that, when added in small amounts to PE, can delay or inhibit the oxidative degradation of plastics. They prevent material aging by capturing free radicals and decomposing hydroperoxides, thus extending the service life of blown film products. Therefore, they are also called "antioxidants." In the blown film process, antioxidants effectively prevent molecular chain breakage caused by thermal oxidation during high-temperature extrusion and film blowing, thereby preventing problems such as decreased mechanical properties, yellowing, and the appearance of "crystal points." They are particularly suitable for film products that require weather resistance and transparency. 3. Now that we have a general understanding of the concept of antioxidants, let's discuss their classification. Antioxidants are categorized into amine antioxidants, phenolic antioxidants, phosphite antioxidants, sulfur-containing antioxidants, biological antioxidants, and compound antioxidants. Each type of antioxidant has its own advantages and specific applications, so we will not discuss them one by one.
4. From the above introduction, you can see that despite their relatively simple functions, antioxidants are actually classified into a very specialized category. So how do we choose the right antioxidant? We need to consider the following principles. First, compatibility. PE material is non-polar, while antioxidant molecules have varying degrees of non-polarity, so compatibility between the two can be challenging. Therefore, it is important to select an antioxidant with good compatibility. Second, migration resistance. Especially for thicker products, since most oxidative degradation occurs at the surface, the antioxidant must be able to continuously migrate from the interior of the film to the outside without causing precipitation. Secondly, stability refers to both the molecular stability of the antioxidant itself and ensuring that it does not react with other additives, thereby affecting the quality of the finished product. Of course, for products that come into contact with food, there are also safety and environmental considerations.
5. Choosing the right antioxidant and the appropriate dosage can be done by consulting the antioxidant manufacturer. Understanding the concept, classification, and selection principles of antioxidants will make communication with them much easier.
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